α-Substituted Benzylic Complexes of Palladium(II) as Precursors of Palladium Hydrides
نویسندگان
چکیده
منابع مشابه
Palladium-Catalyzed α-Arylation of Benzylic Phosphonates
A new synthetic route to access diarylmethyl phosphonates is presented. The transformation enables the introduction of aromatic groups on benzylic phosphonates via a deprotonative cross-coupling process (DCCP). The Pd(OAc)2/CataCXium A-based catalyst afforded a reaction between benzyl diisopropyl phosphonate derivatives and aryl bromides in good to excellent isolated yields (64-92%).
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ژورنال
عنوان ژورنال: Organometallics
سال: 2018
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.8b00066